Epa Design Manual Odor Corrosion Control 800
Ozone disinfection is generally used at medium- to large-sized plants after at least secondary treatment. Another common use for ozone in wastewater treatment is odor control. Continued— What are the advantages and disadvantages of using ozone disinfection? Advantages • Ozone is more effective than chlorine in destroying viruses and bacteria.
• RT @: ICYMI: The Navier-Stokes equations describe simple, everyday phenomena, like water flowing from a garden hose, yet they • RT @: What happens if you release evenly-distributed particles in the ocean? By on • ( ) Hydrogen Sulfide, Corrosion and BOD5 in Innovyze InfoSewer The control of odorous gases and the corrosion of sewers are the two most important problems in operating wastewater collection systems. Evaluation of existing or potential odor or corrosion problems, and identification of where such problems will occur is, therefore, highly essential.
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In sanitary sewer systems, odors are produced as a result of biological decomposition of organic matter, particularly those containing sulfur and nitrogen, under anaerobic conditions prevailing in the slime layer of gravity pipes, force mains, and wet wells. Hydrogen sulfide (H2S) and ammonia are the only malodorous inorganic gases produced from the decomposition. Bad education 2004 unrated download torrent free. Other odor producing substances include organic vapors such as idoles, skatoles, mercaptans and nitrogen-bearing organics. However, H2S is the most commonly known and prevalent odorous gas associated with domestic wastewater collection and treatment systems. H2S DetectorTM extension for InfoSewer/Pro suite gives wastewater engineers a powerful Operations and Maintenance (O&M) tool to readily model and analyze entire sewer collection systems for sulfide generation and corrosion potential under varying conditions anticipated throughout the life of their systems. Image0019 image0022 Hydrogen sulfide has a characteristic rotten egg odor, is extremely toxic, is corrosive to metals, and is a precursor to the formation of sulfuric acid (which corrodes concrete, lead-based paints, metals, and other materials). The conditions leading to formation of H2S generally favor the production of other odorous organic compounds.
Therefore, investigation of the conditions favoring H2S formation not only helps to quantify the potential for odor generation from other compounds, but also it aids in identifying potential corrosion problems in the collection system. The occurrence of H2S in wastewater collection systems, other than that added from industrial sources and infiltrated groundwater, is primarily the result of the reduction of sulfate ion ( ), one of the most universal anions occurring in natural waters, under anaerobic conditions, as shown by the following reaction. The molecular H2S, formed from sulfate reduction, dissolves in the waste water and dissociates in accordance with reversible ionization reactions, expressed as: The partitioning of the hydrogen sulfide into these components (i.e., (H2S) aqueous, HS- ion, and S= ion) depends primarily on the temperature and the pH of the wastewater, although ionic strength, as represented by dissolved solids or electrical conductivity, also affects the partitioning. The HS- ion and S= ion produce no odors. Some of the aqueous H2S will escape into the sewer atmosphere causing the odor problem.
The concentration of H2S gas in the atmosphere will vary with the concentration of (H2S) aqueous according to Henry’s law. The rate of escape of H2S gas is a function of the difference between the saturation or equilibrium concentration determined by Henry’s law and the actual concentration of H2S in the sewer atmosphere.
The EPA provides the figure below that shows H2S in the sewer atmosphere in equilibrium with the given concentrations of aqueous H2S concentration in the wastewater at the respective temperatures, for a pressure of one atmosphere. Image0052 image0065 Prediction of the rate of sulfide buildup and corrosion potential is an essential element in the design of new sewer systems as well as in the evaluation of existing systems. The rate of sulfide buildup depends on a number of environmental conditions, including, concentration of organic material and nutrients, sulfate concentration, dissolved oxygen (DO), pH, temperature, stream velocity, surface area, and detention (residence) time. Accounting for all these environmental conditions, H2S Detector predicts sulfide buildup in sewer collection systems for gravity sewers, force mains, and wet wells using the Pomeroy-Parkhurst equations.